I'm pretty fond of fuel so when I fill up I try and take on as much as I can but I invariably end up with a modest amount of fuel coming out the vent. My hat ends up smelling of fuel (which is nice) but it seems like a waste.
Typically I fill to the bottom of the fuel cap flange but I always feel it would take a few more gallons if I filled it to the top but that makes no sense if it is going to exhaust out the vent.
How full is full?

