I believe the reason that some of the old grizzled graybeards will still use nitrate and butyrate dope... and even cotton occasionally... is because the ye olde tyme craftsmen can get either a more drum-tight fabric tension, and/or it is easier and faster for them to work during installation. Cotton being a natural material is easier to make it "sing and dance" around strange shapes, and do miraculous things in the right hands. Nitrate dope (cellulose acetate nitrate) is sticky, adheres wonderfully to the structure, shrinks and tautens incredibly, etc. The old school crop duster outfits that did a LOT of fabric work on airplanes every year, and had to get the job done right yesterday, were apparently the last group routinely using cotton and Nitrate on a regular basis. Maybe some of the older AG pilots on this forum can verify that or correct me if that is not true?
But then there's that little Hindenburg problem. The nitrate-doped linen fabric burned almost as fast as the hydrogen did. There were a LOT of survivable crashes that became not survivable because of Nitrate dope, and aluminum pigment powder (the stuff they fireworks out of).
So a long time ago they changed to Nitrate for the first few coats on fabric, and went to Butyrate dope (cellulose acetate butyrate) for the outer four or five layers, because it was somewhat less flammable.
Ray Stits developed a much safer system in the 1960's. It wasn't "fireproof" but they were able to certify it as "will not support combustion". Lives were saved.
Nowdays they have these really safe water-based systems. I haven't used them yet, but our EAA chapter is using Stewart Systems on a chapter project and it looks like it has a lot of advantages over even my old favorite Stits.
All that said, if you are restoring a 1930's era Bucker, and you are trying to do a really accurate museum-class restoration, you have no choice but to take the risk of using the historically correct but less safe materials.
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