There are interviews with Doug Doherty of Era Alaska, of "blow it up!" fame, Paul Roderick of Talkeetna Air Taxi, etc.
They also have some cool walkthroughs of interesting working planes.
Worth checking out: http://oddballpilot.com
A Resource for Pilots Interested in Non-Conventional Careers
Whether you’re just learning how to fly or are an experienced pilot, it’s often a challenge to find new and interesting work. The conventional wisdom is that the best aviation career path begins with building time as a flight instructor, and ends in the left seat of an airliner. There are alternatives.
Hopefully this site will give you some idea of the large variety of non-conventional flying jobs out there. Through interviews, videos, and articles, we’ll try to give you a sense of just what these jobs are actually like, the lifestyles they entail, and how to go about applying for them. Getting hired is up to you.

