With Polyfiber, only the topcoat is catalyzed and only then if you are spraying Aerothane or Ranthane. Polyfiber offers another topcoat called Polytone which is not catalyzed and therefore a standard organic respirator is necessary. The Polytone is not very chemical resistant and has a duller sheen than the other two...While it does have its benefits (i.e. easier to repair, etc.) I think the fact that it is much less chemically resistant is a reason to opt for either the Aerothane or the Ranthane. I personally sprayed PPG Delfleet Evolution for my topcoat after learning this is what Aviat paints their Huskies with...If it is ok for a $200K certified airplane than it is good for my Kitfox. The finish is awesome and I am used to spraying this paint so there was no learning curve.
Again on the respirator, I think the fresh air system is a bit overkill for a one up project. I realize the catalyzed paints are very toxic if inhaled but a correctly fitted organic respirator will keep it out of you lungs for the short durations you will be in the paint booth. If you are doing this all day, every day then yes get a fresh air system, full face mask and complete body suit...for our home brewed jobs, this is overkill in my opinion.
