I've been using a ferry tank type system to extend my range for 20 years, first rule is: don't crash. I've run through the various crash scenarios......and really don't feel that much more at risk then I already do with all the fuel carried right up by my head in the wing tanks.

Sure, in a perfect crash situation, you rip the wings (and their fuel tanks) off and come to an uneventful stop, safe in the fuel less fuselage. But it seems like most crash pics show the wings still on the plane and crumpled up pretty bad, I try not to crash and I feel the risk is acceptable. To each his own there, let's face, carrying fuel is dangerous always no matter how we do it. In my case I'm only talking 8 or 9 gallons.
Run the vent outside and there's no smell.Second rule is ASAP, when the mains run down enough, transfer the fuel carried in the ferry up. That way most of the time I flying around with an empty ferry tank. I like having the extra range when needed, and not the extra weight all the time of more tanks in the wings. Also in my case, I use the ferry tank to get mo mo gas (not a typo, just a bad play on words) as it comes in and out in seconds. It's near enough to being on the CG to not be a huge factor in loading. I simply teed off the bottom of my 3 gallon header tank, which leads to the engine and is fed by the mains (both mains, all the time). I don't care if the fuel pumped by the ferry is going directly to the engine or up into the mains or some combination of both, it doesn't matter.
I have a panel mounted switch with a indicator light showing I'm pumping fuel, and a under my seat but reachable valve, in theory the valve isn't even needed if the built in check valve on my quick disconnect is working, it's just a backup to the check valve. This check valve is bypassed in effect when the disconnect is plugged in, both ends of the disc have auto shut offs. Not aircraft hardware, but marine, good enough for me.
I use mine thusly: I fly along, and as soon as I can, transfer MOST but not all of the fuel in the ferry. Then I fly some more.......knowing I if I screw up my range "calculations",

I still have an hour or so in the ferry tank. I can totally run out my mains, the instant I switch the transfer pump on the engine restarts, I tried it as a test once. Then I can fly some more, only when I see the fuel in the 3 gallon header tank dropping (via it's sight gauge), down to the 1 gallon mark (the tank is tapered, 100% usable) do I really seriously start thinking of ;landing somewhere. Kidding.....except for a couple times, but I damn well knew for a fact exactly how much fuel I had so could plan accordingly. If I ever report I actually had to dead stick it in somewhere due to fuel exhaustion, somebody kick my ass!
One thing I will say relative to safety, I really am liking my expensive Nauta fuel bladder (400 bucks for 9 gallons). It is totally dribble and smell free, and requires NO venting. Like the ABW bush bags, as it empties it flattens out to nothing. It has two handles making it very easy to carry and lash down. I think it would take one hell of an impact to rupture, much more then a aluminum tank. If I was you Whee, I'd sell that tank you have, and go ahead and put the few extra fittings in your system while building, and then later pony up and buy a Nauta, a bit over 500 for a 18 gallon, they get cheaper per gallon the bigger they get. they make any size you want.